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Some of the best movie one-liners and moments weren’t originally written into the script. And the Marvel Cinematic Universe has had its fair share of hilarious banter on set that made it into the movies. Hayley Atwell, who plays Peggy Carter, is responsible for a pretty funny Marvel moment herself. And it has suddenly turned out to be one of the best unscripted Marvel movie moments. Check out what Atwell ad-libbed in Captain America: The First Avenger, which proved hilarious.

That moment when Hayley Atwell touched Chris Evans’ chest

Hayley Atwell has described her absolute favorite scene with Chris Evans in Captain America: The First Avenger in several interviews over the years. Uproxx shared one of her recounts when she described what led to the impromptu and hilarious ad-libbed moment. Remember when Evans stepped out of the super-soldier pod with his beefy new bod for the first time?

Atwell remembers it well since it was the first time she’d actually seen her co-star without a shirt on. In the movie, fans see Peggy Carter’s reaction to a hunky Steve Rogers as total awe. And she hilariously reaches up and taps him on his chiseled and well-sculpted chest. It was a natural reaction the internet still thanks her for and an impulse move that proved to be a funny ad-libbed moment. Watch Mojo even named this scene one of the “best unscripted MCU moments.”

What Atwell’s said about her role since

haylet atwell marvel
Hayley Atwell in Marvel’s ‘Agent Carter’ | Kelsey McNeal/Walt Disney Television via Getty Images

Atwell reprised her Peggy Carter character in several MCU films. After The First Avenger, she made cameo appearances in Captain America: The Winter SoldierAvengers: Age of Ultron, and even Ant-Man. But most connected with her via the ABC series, Agent Carter, where Atwell continued her story post-The First Avenger. But fans still wanted more.

During a CBR interview, Atwell said she wasn’t quite ready to say goodbye to Peggy Carter. And when asked about whether or not Marvel would be pursuing a special or movie, Atwell responded, “give me a movie!” Though fans saw her get her happily ever after in Avengers: Endgame, that still wasn’t the end of her story.

Is she returning as Peggy Carter in the MCU?

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What Convinced Captain America to Stay in the Past with Peggy?

Attention: Spoiler alert for anyone who hasn’t yet watched the new Doctor Strange in the Multiverse of Madness.

Those who did catch the latest MCU adventure on the big screen saw Captain Carter make an appearance, as Screen Rant described. Things didn’t end well for her upon an encounter with the Scarlet Witch. But while this ending seems final, fans may not have seen the last of Captain Carter or Atwell. Given that the multiverse remains a factor, shows like What If…? have brought back deceased characters. So there are a host of different scenarios that will make it possible for Atwell to remain a pivotal part of the MCU story even beyond a few occasional appearances.